Selection of elastomeric membranes for the removal of volatile organics from water

A wide range of homogeneous elastomeric membranes has been prepared using dicumylperoxide as a general cross-linking agent. The membranes have been used for both equilibrium sorption measurements and steady-state pervaporation experiments to study solution-diffusion phenomena in the removal of volatile organic components from aqueous solutions. Pervaporation experiments have been performed under identical hydrodynamic conditions in order to fix the boundary layer mass transfer coefficient at a constant and known value. For comparison of the permeabilities of different pervaporation membrane materials, this is of utmost importance. A wide range of selectivity factors up to a value of 100,000 are obtained, whereas usually the permeabilities for the organic component are in the range of 10-10-10-9m2/s and 10-14-10-12m2/s for water. The permeation and sorption data obtained for the various elastomers have been related to the chemical and physical nature of the elastomers through the solubility parameter and the glass transition temperature, respectively. Both diffusional and sorption effects seem to be important, determining the water-transport behavior in the elastomeric membranes. The solubility of the organic component appears to be independent of this combined solubility parameter. Differences in the permeabilities of the organic component can primarily be ascribed to structural parameters in the membrane material, like degree of unsaturation and presence of steric side groups

Finite element models applied in active structural acoustic control

This paper discusses the modeling of systems for active structural acoustic control. The finite element method is applied to model structures including the dynamics of piezoelectric sensors and actuators. A model reduction technique is presented to make the finite element model suitable for controller design. The reduced structural model is combined with an acoustic model which uses the radiation mode concept. For a test case consisting of a rectangular plate with one piezo patch the model reduction technique is validated. The results show that the an accurate prediction of both the structural and acoustic response is predicted by the reduced model. The model is compact requiring small simulation times, which makes it attractive for control system design. Finally the control performances for both structural and acoustic error criteria are presented

Optimization strategy for actuator and sensor placement in active structural acoustic control

In active structural acoustic control the goal is to reduce the sound radiation of a structure by means of changing the vibrational behaviour of that structure. The performance of such an active control system is to a large extent determined by the locations of the actuators and sensors. In this work an approach is presented for the optimization of the actuator and sensor locations. The approach combines a numerical modelling technique, for predicting the control performance, and genetic optimization, to find the optimal actuator and sensor locations. The approach is tested for a setup consisting of clamped rectangular plate with a piezoelectric actuator and either structural or acoustic sensors. The results show that a control system with optimal actuator and sensor configuration outperforms an arbitrary chosen configuration in terms of reduction in radiated sound power

Selection of elastomeric membranes for the removal of volatile organics from water

A wide range of homogeneous elastomeric membranes has been prepared using dicumylperoxide as a general cross-linking agent. The membranes have been used for both equilibrium sorption measurements and steady-state pervaporation experiments to study solution-diffusion phenomena in the removal of volatile organic components from aqueous solutions. Pervaporation experiments have been performed under identical hydrodynamic conditions in order to fix the boundary layer mass transfer coefficient at a constant and known value. For comparison of the permeabilities of different pervaporation membrane materials, this is of utmost importance. A wide range of selectivity factors up to a value of 100,000 are obtained, whereas usually the permeabilities for the organic component are in the range of 10-10-10-9m2/s and 10-14-10-12m2/s for water. The permeation and sorption data obtained for the various elastomers have been related to the chemical and physical nature of the elastomers through the solubility parameter and the glass transition temperature, respectively. Both diffusional and sorption effects seem to be important, determining the water-transport behavior in the elastomeric membranes. The solubility of the organic component appears to be independent of this combined solubility parameter. Differences in the permeabilities of the organic component can primarily be ascribed to structural parameters in the membrane material, like degree of unsaturation and presence of steric side groups

Removal of trace organics from aqueous solutions. Effect of membrane thickness

A resistance-in-series model is used to describe the pervaporation performance of elastomeric membranes in the removal of volatile organic components from water. Equations have been derived to describe the organic component flux as a function of feed concentration, permeability of the organic component in the membrane, membrane thickness and liquid boundary layer mass transfer coefficient. The model has been verified using both homogeneous and composite membranes of polydimethylsiloxane, ethylene propylene rubber and polyoctenamer. Membranes with a wide range of thicknesses have been prepared and the pervaporation behaviour for the removal of toluene and trichloroethylene from aqueous solutions has been studied. The experiments show that the hydrodynamic boundary layer resistance is of great importance. For highly permeable polymers such as polydimethylsiloxane mass transfer in the boundary layer is rate determining and should be considered carefully in further development of the process. For less permeable polymers such as ethylene propylene rubber this effect becomes more dominant with decreasing membrane thickness. The water fluxes are inversely proportional to the thickness of the actual separating layer and they depend strongly on the type of elastomer used. A proper choice of the elastomeric material and the thickness of the separating layer will determine the selectivity of the process

Extraction of secondary metabolites from plant material: a review

This review article intends to give an overview of the developments in the extraction technology of secondary metabolites from plant material. There are three types of conventional extraction techniques. In order of increasing technological difficulty, these involve the use of solvents, steam or supercritical fluids. Each of these types of extraction methods is described in detail with respect to typical processing parameters and recent developments. Following the discussion of some technical and economic aspects of conventional and novel separation processes, a few general conclusions about the applicability of the different types of extraction techniques are drawn